Miller Indices

In this lecture, we are going to learn about the Miller Indices, the definition of it, the Procedure for finding Miller Indices, and some important features of Miller Indices of crystal plane. So let’s start with the introduction of Miller Indices.

Introduction of Miller Indices

In a crystal, there exists direction and planes which contain a large concentration of atoms. Therefore it is necessary to locate these directions and planes for a crystal to analyze. The problem is that, hoe to identify the direction and to designate ( to choose) a plane in a crystal.

Here, let us discuss briefly the method of designating a plane in crystal. This method was suggested by Miller.

Miller Indices

Miller introduces a set of three numbers to designate a plane in a crystal. This set of three numbers in known as Miller indices of the concerned plane.

Procedure for Finding Miller Indices

The steps in the determination of Miller indices of a plane are illustrated with the aid of Figure. Consider the plane ABC which cuts 1 unit along the X-axis, 2 units along the Y-axis, and three units along the Z-axis.

Step 1:

• Find the intercept of the plane ABC along the three axes X, Y, and Z. Let it be OA, OB, and OC. Express the intercepts in terms of multiples of axial lengths, i.e., lattice parameters. Let them be OA = pa, OB = qb, and OC = rc where p, q, and r are the intercept numerical values along the three-axis.

• In this example shows:

p=1, q=2 and r = 3

Hence, OA : OB: OC = pa:qb: rc = 1a: 2b : 3c

• Therefore, the intercepts are 1a, 2b, and 3c along the three axes.

Step 2:

• Find the reciprocal of the numerical intercept values.

i.e., \frac{1}{p}\frac{1}{q}\frac{1}{r}

• For the example shown the reciprocal of the numerical intercept values are:

\frac{1}{1}\frac{1}{2}\frac{1}{3}

Step 3:

• Convert these reciprocals into whole numbers by multiplying each with their least common multiple (LCM). In this example, the LCM is 6. Therefore,

6\times \frac{1}{1}\;,6\times \frac{1}{2}\;, 6\times\frac{1}{3}
6 \;3\; 2

Step 4:

• Enclose these numbers in the bracket. This represents the indices of the given plane and is called the Miller Indices of the plane.

• For example, shown, the miller indices are (6 3 2).

• It is generally denoted by ( h k l). It can also be notices that,

h:k:l=\frac{1}{1}:\frac{1}{2}:\frac{1}{3}

Definition -1: Thus, Miller indices may be defined as the reciprocal of the intercepts made by the plane along the three crystallographic axes which are reduced to the smallest numbers.

Definition-2: Miller Indices are the three smallest possible integers, which have the same ratio as the reciprocals of the intercepts of the plane concerned along the three axes.

Important Features of Miller Indices of Crystal Plane

For the cubic crystal especially, the important features of Miller indices are:

1. For an intercept at infinity, the corresponding index is zero, that is, if a plane is parallel to any one of the coordinate axis, then its intercept is at infinity. Hence, the Miller index for that axis is zero.
2. All equally spaced parallel planes have the same Miller indices (h k l) or vice versa, that is, if the Miller indices of two planes have the same ratio like (8 4 4), (4 2 2), and (2 1 1) then the planes are parallel to each other.
3. The indices (h k 1) do not define a particular plane, but a set of parallel planes.
4. It is only the ratio of the indices which is important in this notation.
5. If a plane cuts the axis on the negative side of the origin, the corresponding index is negative.

Frequently Asked Questions on Miller Indices

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